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Following an ultimatum delivered by the lead government negotiator, the head opposition negotiator has condemned terrorism but does not lead a united front.
Video: Frequent violation of the ceasefire in Syria provokes doubts over the Assad regime's commitment to Geneva talks.
The UN sought on Friday to get a new round of Syrian peace talks off the ground, but there were few signs of progress amid dozens more civilian deaths.
Second day of UN-backed Syria mediation talks begins on Friday as envoy Staffan de Mistura urged an end to the conflict which has killed hundreds of thousands and displaced millions.
Nearly 70 fighters have been killed in clashes between two formerly allied extremist groups in northern Syria's Idlib province, the Syrian Observatory for Human Rights said Tuesday.
Islamic State group militants blew up the Hayyan gas plant in the eastern Homs province over the weekend, the Syrian Observatory for Human Rights said on Monday.
Buoyed by victory in Aleppo, the Syrian regime appears keen to press home military advantages around Damascus. Wadi Barada, which supplies the capital with water, is the next target
Pro-Syrian opposition protests re-ignited on Friday across rebel-held parts of the country, as people took to the street to reject a new ceasefire agreement, brokered by Iran, Turkey and Russia.
A Russian-Turkish brokered deal, which came into place on Thursday night is largely holding despite some bombing and skirmishes.
Some 3,000 people were evacuated from east Aleppo on Thursday under a new deal struck between rebels and regime forces, while another 50,000 people remain trapped in the city.